RIAs mean passing data around and XML is one of the big flavors for doing this.
Here is some good information on using them.
http://msdn2.microsoft.com/en-us/library/aa302298.aspx
http://www.lovettsoftware.com/blogs/blog.aspx?id=57
http://blogs.msdn.com/kaevans/archive/2006/02/20/535578.aspx
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